If there is a desktop site option available, typically towards the bottom of a page, select this option to switch to desktop view.
Alternatively, from within Chrome select the overflow menu and place a checkmark next to Request desktop site.
Enter the URL to the desktop page and it should load the desktop site.
This applies only to sites where the page automatically directs you to the mobile version of the website.
Some pages do not allow you to view the desktop site when viewing content on a mobile device.